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ALASKAN-TYPE
Pt+/-Os+/-Rh+/-Ir
by Graham T. Nixon British Columbia Geological Survey |
Ref: ultramáfica, alaska, magnetita, cromita, platina, ósmio, irídio
Nixon, G. T. (1996): Alakan-type Pt+/-Os+/-Rh+/-Ir, in Selected British Columbia Mineral Deposit Profiles, Volume 2 - Metallic Deposits, Lefebure, D.V. and Hõy, T, Editors, British Columbia Ministry of Employment and Investment, Open File 1996-13, pages 113-116.
IDENTIFICATION
SYNONYMS: Zoned ultramafic, Uralian-type, Alaskan-type.COMMODITIES (BYPRODUCTS): Pt (Ir, Os, Rh, magnetite).
EXAMPLES (British Columbia - Canada/International): Tulameen Complex and associated placers; magnetite plus trace platinum group elements (PGE) -Lodestone Mountain (092HSE034), Tanglewood Hill (092HSE035); chromite - Grasshopper Mountain (092HNE011); olivine - Grasshopper Mountain Olivine (092HNE189); Red Mountain, Goodnews Bay (Alaska, USA), Tin Cup Peak (Oregon, USA), Ural Mountains and Aldan Shield (Russia), Fifield district (NSW, Australia).
GEOLOGICAL CHARACTERISTICS
CAPSULE DESCRIPTION: Ultramafic intrusive complexes, commonly zoned,
forming sills, stocks or intrusive bodies with poorly known external geometry.
Subeconomic platinum group elements in lode occurrences are associated with: 1)
thin (centimetre-scale), disrupted chromitite layers , 2) thick (metre-scale)
concentrations of cumulus magnetite or 3) clinopyroxenite. Economic placer
deposits appear to be derived predominantly from chromitite- hosted PGE
occurrences.TECTONIC SETTINGS: Traditionally subdivided into orogenic (unstable) and platformal (stable) environments. In British Columbia, Alaskan-type complexes were emplaced during an episode of Cordillera-wide, subduction-related arc magmatism followed by an episode of orogenic compression.
DEPOSITIONAL ENVIRONMENT / GEOLOGICAL SETTING: Zoned to crudely layered ultramafic- mafic intrusive complexes with rarely preserved (or poorly documented) metamorphic aureoles. Intrusive margins are commonly faulted. Traditionally viewed as deep-seated cumulates diapirically re-emplaced at high levels in the crust. In British Columbia, at least, most intrusions appear to represent cumulate deposition in upper crustal (subvolcanic?) magma chambers and the diapiric re-emplacement model lacks definitive supporting evidence.
AGE OF MINERALIZATION: Precambrian to late Mesozoic; most Alaskan-type complexes in British Columbia appear to be mid-Triassic to late Early Jurassic in age.
HOST/ASSOCIATED ROCK TYPES: Predominantly dunite, wehrlite, olivine clinopyroxenite, clinopyroxenite, hornblende clinopyroxenite, clinopyroxene hornblendite, hornblende- and/or clinopyroxene-bearing gabbro/diorite. Minor lithologies include chromitite, magnetitite, olivine-hornblende clinopyroxenite, and hornblendite. Associated feldspar-bearing lithologies include gabbro/diorite, monzonite, monzodiorite and minor alkali-feldspar syenite and hornblende- feldspar ± quartz ± biotite pegmatite.
DEPOSIT FORM: Lode occurrences of PGEs are primarily controlled by magmatic cumulate stratigraphy:
- 1) chromitites are restricted to dunites where they form thin
discontinuous layers or schlieren, pods and nodular masses seldom more than a
metre in length;
2) magnetitites and concentrations of cumulus magnetite form well bedded, locally continuous layers up to six m thick intercalated with hornblende clinopyroxenite;
3) lenses and vein-like bodies of relatively coarse-grained or "pegmatoid", biotite and magnetite-poor, PGE-bearing clinopyroxenites are enclosed by finer grained, biotite and magnetite-rich, PGE-poor clinopyroxenites.
ORE MINERALOGY (Principal and subordinate): Three types of PGE mineral (PGM) associations are recognized in lode occurrences: 1) chromitite-PGM association, principally chromite and Pt-Fe(-Cu-Ni) alloys (e.g. tetraferroplatinum, isoferroplatinum, rare native platinum, tulameenite) and minor Os-Ir and Pt-Ir alloys, Rh-Ir sulpharsenides (hollingworthite-irarsite series), sperrylite (PtAs2), geversite (PtSb2), and laurite (RuS2); 2) magnetitite-PGM association (not well documented), principally magnetite (Ti-V-rich in certain cases) and Pt-Fe and Os-Ir alloys, and rare cooperite (PtS); 3) clinopyroxenite-PGM association (known from a single locality - Fifield, NSW, Australia), principally Pt-Fe alloys (isoferroplatinum-tetraferroplatinum), erlichmanite (OsS2), cooperite, and sperrylite-geversite. Minor amounts of base metal sulphides (chalcopyrite, pentlandite, pyrrhotite, pyrite, bornite, violarite, bravoite, millerite, heazlewoodite) generally accompany the PGM in all three associations.
GANGUE MINERALOGY (Principal and subordinate): The principal gangue minerals include olivine, chrome spinel, clinopyroxene, and hornblende in ultramafic rocks; hornblende, clinopyroxene and plagioclase in gabbroic/dioritic rocks; and hornblende, quartz (rare) and alkali feldspar in leucocratic differentiates. Orthopyroxene is characteristically absent as a cumulus phase but may form very rare intercumulus grains. Accessory magnetite and apatite are generally common, and locally abundant in hornblende clinopyroxenite; sphene and zircon occur in felsic differentiates; phlogopite-biotite is particularly widespread as an accessory phase in British Columbia.
ALTERATION MINERALOGY: Secondary PGM are minor and closely associated with the primary PGM alloys. Remobilization of PGE is believed to be extremely limited and may be commonly related to postmagmatic serpentinizaton processes acting during regional metamorphism and deformation.
WEATHERING: It has been argued by some that the PGE found in placer occurrences may owe their origin to the hydromorphic dispersion and precipitation of PGE during normal weathering processes. The debate continues, but it is clear from a variety of textural, mineralogical and isotopic (Re-Os) data that the common placer PGE occurrences are the products of mechanical degradation of magmatic lode occurrences and not surficial remobilization processes.
ORE CONTROLS: The PGM appear to be restricted to chromitite, magnetite-rich or clinopyroxenite layers which formed by primary magmatic crystallization processes. The chromite is typically associated with dunite whereas the magnetite is found with clinopyroxenite.
GENETIC MODEL: The origin of the PGE in Alaskan-type deposits is magmatic with very limited low-temperature remobilization. A low sulphidation, relatively high oxidation magmatic environment (subduction-related?) appears to be an important genetic control. The chromitites in dunite and, to a much lesser extent, the magnetite-rich layers in clinopyroxenite, appear to be the ultimate source of the placer PGE.
ASSOCIATED DEPOSIT TYPES: Placer deposits (C01, C02) are extremely important since they have been the only significant economically recoverable source of PGE associated with Alaskan-type complexes. Some lode deposits have been worked in Russia but their documentation is extremely poor.
COMMENTS: All of the world's most important Alaskan-derived placers appear to be related to concentrations of PGE in chromitites. Gold in these placers appears to have been derived from a separate source. Magnetite accumulations in clinopyroxenites of the Tulameen Complex have been explored for magnetite. EXPLORATION GUIDES
GEOCHEMICAL SIGNATURE: Primarily Pt, with subsidiary Os, Rh and Ir; other elements such as Cu, Ni, and Cr may be locally important. Geochemical pathfinder elements for PGE, such as As and Sb, may also be important.
GEOPHYSICAL SIGNATURE: Primarily magnetic; gravity may be important.
OTHER EXPLORATION GUIDES: Stream sediment sampling of heavy mineral concentrates for PGE is a key exploration tool; in favourable circumstances PGE geochemistry and platinum nugget mineralogy can uniquely distinguish an Alaskan-type heritage from all other common PGE environments.
ECONOMIC FACTORS
TYPICAL GRADE AND TONNAGE: PGE concentrations in grab samples from
lode deposits are extremely spotty such that reliable tonnages and grades are
not available. The associated placer deposits are likewise extremely variable.
Maximum grade of Pt from the Goodnews Mining Company records, Alaska (1957) was
approximately “$37 per cubic yard” at February 1993 prices. Placers in the
Tulameen district reportedly yielded some 620 kg of impure platinum between 1889
and 1936. Some of the placer deposits in the former Soviet Union have yielded
exceptional platinum nuggets of up to 11.3 kg.ECONOMIC LIMITATIONS: The chromitite-PGE association appears to be the most important in British Columbia; without exception, all of these chromitite occurrences are small, dispersed throughout a dunite host, and all have been remobilized soon after deposition within the high-temperature magmatic environment. A small open pit operation appears to be the only potentially economic method of PGE extraction. The occurrence of the PGE as small micrometre-size inclusions in refractory chromite poses problems for processing.
END USES: PGE are primarily used as high-temperature catalysts in a variety of industries, perhaps the most familiar being platinum for automobile catalytic converters. Other uses include medical and electronic (fuel cells, thermocouples), and platinum is used in jewelry.
IMPORTANCE: PGE are classed as a strategic commodity. The most important producers are South Africa and Russia.
REFERENCES