terça-feira, 10 de maio de 2016

SEIS LAGOS THE LARGEST NIOBIUM RESERVE IN THE WORLD IS STILL WAITING TO BE DEVELOPED

SEIS LAGOS THE LARGEST NIOBIUM RESERVE IN THE WORLD IS STILL WAITING TO BE DEVELOPED

By Pedro Jacobi 


In the middle of the Amazon, 60km away from the Venezuelan border and 2km from a local road is the location of the largest Niobium deposit on the Earth.
It is  called Seis Lagos and, believe it or not,  is still waiting for the Brazilian Government’s decision to let miners extract and redistribute its enourmouswealth.
INTRODUCTION
In 1975, during a geological mapping program, CPRM's geologists discovered the remarkable structures of Seis Lagos Alkaline Complex intruded in gneissic terrain. It comprises three different intrusive bodies.
Seis Lagos Property at the Amazonas State is the world’s largest niobium reserve of 2,897Mt @ 2.81% Nb2O5 or 81Mt of Nb2O5 and, possibly, a very large titanium and rare earths deposit.
click the picture to enlarge
The company that acquires this property will be in a position to control the largest niobium reserves in the world, and, likely become the main player in a very important, fast growing, industrial mineral market.
THE ELEMENT
The element niobium (Nb), also named columbium, was discovered in 1802.  Niobium is quite abundant in nature being present in the earth’s crust at the level of 24ppm.  Its fusion point is high at 2468oC.
INDUSTRIAL USES
 Due to its favourable high-temperature strength and good low temperature ductility, niobium has been used as a prime material for the aerospace industries.
 This metal is mostly used in special steels, microalloys and superalloys, automobile industry, nuclear reactors, catalizers, acoustics, electrooptics, high temperature applications, glass manufacture and superconductors.  It is a versatile element which is considered to be the best way of accomplishing many technological goals in a most cost effective way.  Modern niobium technology is replacing the use of several metals such as molybdenum, vanadium, nickel, chromium, copper and titanium in many industrial applications.
 CBMM’s main product is the iron-niobium (65%Nb) alloy which is used as an important element in the high-strength low alloy steels, stainless steels and niobium pentoxide.  Metallic niobium is used together the titanium in a NbTi alloy which is used in an important superconductor material.
THE MINERAL
Pyrochlore (A2-mB2O6(O,OH,F)1-n.pH2O), probably the most abundant niobium mineral, has a extremely variable composition and occurs mainly in carbonatites.  The pyrochlore group also includes betafite (2Ti>Nb+Ta), microlite (Nb+Ta>2Ti) and bariumpyrochlore which is the ore mineral at Araxá.  Columbite is the second most important mineral of niobium and is, mainly, associated to pegmatites and tin bearing granites.
THE HOST ROCKS
Carbonatites are specialised intrusive magmatic rocks which are important sources of niobium, rare earths, titanium, copper, vermiculite and phosphates.
In Brazil the extremely high grades of niobium and titanium in the deposits is a result of an intense leaching of the carbonatite which caused a well developed lateritic profile that can be as deep as 300m.
WORLD RESERVES
Total world reserves of Nb2O5 are estimated at 5.4Mt (excluding the Seis Lagos deposit) being 88% in Brazilian soil.
Known ore reserves, at the most important producing mines, are 464Mt @ 2.5% Nb2O5 at Araxá (Brazil) and 16Mt @ 0.68% Nb2O5 at St-Honoré (Canada).  Other niobium resources are reported from Tapira (179Mt @ 0.67% Nb2O5), Catalão (1.4Mt @ 2.19% Nb2O5) and Salitre (Brazil), Lueshe Lake, Panda Hill, Chilwa Island and Kalubwe (Africa), James Bay, Nemegosenda, Lackner Lake, Oka (6.3Mt @ 0.32% Nb2O5) and Manitou Island in Canada.
MINING
The St Honoré carbonatite complex (Cambior) hosts the most important niobium mine outside Brazil.  This is an underground deposit of low grade (0.67% Nb2O5 ) where mining is executed by means of open stope and pillar.  The mine depth surpasses 400m.
On the other hand, on the Araxá deposit, which belongs to CBMM, and combines the world’s largest reserve (excluding Seis Lagos) and highest grade (2.5% Nb2O5) , the ore is mined by open pit methods.
In Brazil, due to the deep weathering of the carbonatite, blasting is not required and mining costs are much lower than Canada.
METALLURGY
Brazil has a leading position in technological development of special niobium alloys.  The ore, at Araxá, is crushed, concentrated through grinding, magnetic separation, desliming and flotation to 60% Nb2O5 .  The flotation concentrates are then treated in a calcining and leaching plant.  The standard ferroniobium is produced by means of a new metallurgical process improved by CBMM, the aluminothermic reduction.
PRICES
The Niobium price is been stable around 3-7US$/pound as can be seen on the graph.
MAIN MARKETS
There are more than 300 smelters world wide that use niobium in their production:
CONSUMPTION PATTERN FOR NIOBIUM IN THE USA
(US BUREAU OF MINES - 1,000 LBS.)

1970
% OF TOTAL 1970
1971
1972
1973
1974
1975
1976
1977
1978
1979
1980
% OF TOTAL 1980
STEEL













Carbon & HSLA
705
26
821
1874
2180
2291
1796
1882
2350
3011
3178
3204
48
Stainless Steel
522
19
588
644
712
564
379
491
588
805
827
696
10
Full alloy Steel
829
31
789
302
361
511
372
538
584
656
505
476
7
Steel Totals
2056
76
2198
2820
3253
3366
2547
2911
3522
4472
4510
4376
65
Superalloys
472
17
591
665
685
1097
359
423
796
1146
1777
1904
29
Other Alloys
36
1
37
57
67
82
35
50
65
60
32
15
-
Miscellaneous
24
1
51
131
48
78
78
50
20
16
17
7
-
Primary Totals
2588
95
2877
3673
4053
4623
3019
3434
4403
5694
6336
6302
94
Niobium Metal
119
4
115
251
262
161
108
99
190
225
331
346
5
Grand Total
2707
99
2992
3924
4315
4784
3127
3533
4593
5919
6667
6648
99
The main buyers of CBMM’s production are Nippon Steel, Mannesman (Germany), Ilva Spa (Italy), LVT steel (US), Usiminas, Cosipa and Gerdau.
SPECIFIC NIOBIUM CONSUMPTION-KILO/METRIC TON
RAW STEEL PRODUCED

1973
1974
1975
1976
1977
1978
1979
USA
0108
0116
0118
0113
0140
0163
0166
Canada
0440
0324
0300
0326
0382
0436
0415
Japan
0068
0100
0142
0147
0136
0133
0138
Austria
0214
0096
0239
0178
0220
0267
0378
Belgium/Luxemburg
0093
0133
0096
0116
0077
0046
0066
France
0104
0130
0201
0168
0190
0193
0207
Germany
0158
0253
0275
0225
0226
0298
0340
Italy
0310
0318
0446
0484
0391
0346
0338
Netherlands
0161
0126
0177
0106
0112
0071
0086
Spain
0056
0052
0113
0118
0071
0088
0086
Sweden
0561
0567
0661
0500
0438
0279
0213
UK
0225
0286
0283
0228
0229
0246
0186
Australia
0091
0094
0127
0128
0137
0171
0185
Brasil
0160
0287
0387
0201
0170
0168
0339
So. Africa
0123
0155
0132
0127
0151
0089
0148
Cambior (Canada) sells to Canada, US and Japan. while Mineração Catalão (Anglo American Corporation) sales are directed mostly to US and Germany.
FUTURE TRENDS AND USES
Niobium  has been promoted, during the last 20 years into a very important component of the world steel industry.  Forecasters are predicting that the consumption will continue growing at the rate of 8-10%.

PREDICTED WORLD HIGH PURITY NIOBIUM METAL CONSUMPTION, 1981-2000


1981-1985
1986-2000

1
NMR AND LAB MAGNETS
25
175

2
HEP
40
80

3
COMPUTERS AND INSTRUMENTATION
2
18

4
MAGNETIC SEPARATION
1
2

5
SMES
4
16

6
LEVITATED TRAINS
-
4
subject to 1985 decision
7
SHIP PROPULSION
1
9

8
CURRENT LIMITERS
1
4

9
POWER TRANSMISSION
Negligible
70
mainly after 1944
10
SUPERCONDUCTING GENERATORS
1
11

11
FUSION
20
230

12
MHD
2
65

13
DEFENSE
5
50

14
GYROTRONS, ISOTOPE SEPARATORS
1
3


TOTAL
103
737

SEIS LAGOS, THE LARGEST RESOURCE
In 1975, during a geological mapping programme CPRM’s geologists discovered the remarkable structures of Seis Lagos Alkaline Complex intruded in gneissic terrain.  It comprises three different intrusive bodies.  Only in 1982 that company started a detailed exploration programme.
The main carbonatite is an outstanding topographic feature which stands 300m above the local surface (see picture).
Seis Lagos main structure has a 5km diameter and is situated at the São Gabriel da Cachoeira municipality at the Amazonas State, only 60km away from the Venezuelan border and 2km from a local road.  Seis Lagos is 97km from S. Gabriel port by the Negro River 900km upstream from Manaus.
The carbonatite is, also, characterized by its strong thorium anomaly which peaks at 35.344cps against a 1.300cps local background.
An intense supergene leaching process developed a 250m deep weathering profile.  This is the main reason why this deposit is so rich in niobium (2.81% Nb2O5), titanium and rare earths.
At Seis Lagos the niobium is present in minerals such as niobium-rutile and niobium-brookite together with florencite and crandalite (rare earths).
This unusual mineralogy is a result of the destruction of pyrochlore during the supergene process causing the free niobium to combine with oxigen, forming these oxides.  Niobium may be, also, in the structure of other supergene minerals such as goethite and hematite.
Technological studies have been made by CPRM and, apparently, the ore is amenable to treatment using known technology.  A technical report done by INBRACEL confirms that the use of SAM for direct reduction of Seis Lagos ore will allow the introduction of niobium in common low carbon steels, at a very low price, which may change all the economicity of this metal.
Reserves, calculated by CPRM, after a preliminary drilling programme, are listed below.
RESERVES

SEIS LAGOS THE LARGEST NIOBIUM RESERVE IN THE WORLD IS STILL WAITING TO BE DEVELOPED


By Pedro Jacobi

In the middle of the Amazon, 60km away from the Venezuelan border and 2km from a local road is the location of the largest Niobium deposit on the Earth.
It is  called Seis Lagos and, believe it or not,  is still waiting for the Brazilian Government’s decision to let miners extract and redistribute its enourmouswealth.
INTRODUCTION
In 1975, during a geological mapping program, CPRM's geologists discovered the remarkable structures of Seis Lagos Alkaline Complex intruded in gneissic terrain. It comprises three different intrusive bodies.
Seis Lagos Property at the Amazonas State is the world’s largest niobium reserve of 2,897Mt @ 2.81% Nb2O5 or 81Mt of Nb2O5 and, possibly, a very large titanium and rare earths deposit.
click the picture to enlarge
The company that acquires this property will be in a position to control the largest niobium reserves in the world, and, likely become the main player in a very important, fast growing, industrial mineral market.
THE ELEMENT
The element niobium (Nb), also named columbium, was discovered in 1802.  Niobium is quite abundant in nature being present in the earth’s crust at the level of 24ppm.  Its fusion point is high at 2468oC.
INDUSTRIAL USES
 Due to its favourable high-temperature strength and good low temperature ductility, niobium has been used as a prime material for the aerospace industries.
 This metal is mostly used in special steels, microalloys and superalloys, automobile industry, nuclear reactors, catalizers, acoustics, electrooptics, high temperature applications, glass manufacture and superconductors.  It is a versatile element which is considered to be the best way of accomplishing many technological goals in a most cost effective way.  Modern niobium technology is replacing the use of several metals such as molybdenum, vanadium, nickel, chromium, copper and titanium in many industrial applications.
 CBMM’s main product is the iron-niobium (65%Nb) alloy which is used as an important element in the high-strength low alloy steels, stainless steels and niobium pentoxide.  Metallic niobium is used together the titanium in a NbTi alloy which is used in an important superconductor material.
THE MINERAL
Pyrochlore (A2-mB2O6(O,OH,F)1-n.pH2O), probably the most abundant niobium mineral, has a extremely variable composition and occurs mainly in carbonatites.  The pyrochlore group also includes betafite (2Ti>Nb+Ta), microlite (Nb+Ta>2Ti) and bariumpyrochlore which is the ore mineral at Araxá.  Columbite is the second most important mineral of niobium and is, mainly, associated to pegmatites and tin bearing granites.
THE HOST ROCKS
Carbonatites are specialised intrusive magmatic rocks which are important sources of niobium, rare earths, titanium, copper, vermiculite and phosphates.
In Brazil the extremely high grades of niobium and titanium in the deposits is a result of an intense leaching of the carbonatite which caused a well developed lateritic profile that can be as deep as 300m.
WORLD RESERVES
Total world reserves of Nb2O5 are estimated at 5.4Mt (excluding the Seis Lagos deposit) being 88% in Brazilian soil.
Known ore reserves, at the most important producing mines, are 464Mt @ 2.5% Nb2O5 at Araxá (Brazil) and 16Mt @ 0.68% Nb2O5 at St-Honoré (Canada).  Other niobium resources are reported from Tapira (179Mt @ 0.67% Nb2O5), Catalão (1.4Mt @ 2.19% Nb2O5) and Salitre (Brazil), Lueshe Lake, Panda Hill, Chilwa Island and Kalubwe (Africa), James Bay, Nemegosenda, Lackner Lake, Oka (6.3Mt @ 0.32% Nb2O5) and Manitou Island in Canada.
MINING
The St Honoré carbonatite complex (Cambior) hosts the most important niobium mine outside Brazil.  This is an underground deposit of low grade (0.67% Nb2O5 ) where mining is executed by means of open stope and pillar.  The mine depth surpasses 400m.
On the other hand, on the Araxá deposit, which belongs to CBMM, and combines the world’s largest reserve (excluding Seis Lagos) and highest grade (2.5% Nb2O5) , the ore is mined by open pit methods.
In Brazil, due to the deep weathering of the carbonatite, blasting is not required and mining costs are much lower than Canada.
METALLURGY
Brazil has a leading position in technological development of special niobium alloys.  The ore, at Araxá, is crushed, concentrated through grinding, magnetic separation, desliming and flotation to 60% Nb2O5 .  The flotation concentrates are then treated in a calcining and leaching plant.  The standard ferroniobium is produced by means of a new metallurgical process improved by CBMM, the aluminothermic reduction.
PRICES
The Niobium price is been stable around 3-7US$/pound as can be seen on the graph.
MAIN MARKETS
There are more than 300 smelters world wide that use niobium in their production:
CONSUMPTION PATTERN FOR NIOBIUM IN THE USA
(US BUREAU OF MINES - 1,000 LBS.)

1970
% OF TOTAL 1970
1971
1972
1973
1974
1975
1976
1977
1978
1979
1980
% OF TOTAL 1980
STEEL













Carbon & HSLA
705
26
821
1874
2180
2291
1796
1882
2350
3011
3178
3204
48
Stainless Steel
522
19
588
644
712
564
379
491
588
805
827
696
10
Full alloy Steel
829
31
789
302
361
511
372
538
584
656
505
476
7
Steel Totals
2056
76
2198
2820
3253
3366
2547
2911
3522
4472
4510
4376
65
Superalloys
472
17
591
665
685
1097
359
423
796
1146
1777
1904
29
Other Alloys
36
1
37
57
67
82
35
50
65
60
32
15
-
Miscellaneous
24
1
51
131
48
78
78
50
20
16
17
7
-
Primary Totals
2588
95
2877
3673
4053
4623
3019
3434
4403
5694
6336
6302
94
Niobium Metal
119
4
115
251
262
161
108
99
190
225
331
346
5
Grand Total
2707
99
2992
3924
4315
4784
3127
3533
4593
5919
6667
6648
99
The main buyers of CBMM’s production are Nippon Steel, Mannesman (Germany), Ilva Spa (Italy), LVT steel (US), Usiminas, Cosipa and Gerdau.
SPECIFIC NIOBIUM CONSUMPTION-KILO/METRIC TON
RAW STEEL PRODUCED

1973
1974
1975
1976
1977
1978
1979
USA
0108
0116
0118
0113
0140
0163
0166
Canada
0440
0324
0300
0326
0382
0436
0415
Japan
0068
0100
0142
0147
0136
0133
0138
Austria
0214
0096
0239
0178
0220
0267
0378
Belgium/Luxemburg
0093
0133
0096
0116
0077
0046
0066
France
0104
0130
0201
0168
0190
0193
0207
Germany
0158
0253
0275
0225
0226
0298
0340
Italy
0310
0318
0446
0484
0391
0346
0338
Netherlands
0161
0126
0177
0106
0112
0071
0086
Spain
0056
0052
0113
0118
0071
0088
0086
Sweden
0561
0567
0661
0500
0438
0279
0213
UK
0225
0286
0283
0228
0229
0246
0186
Australia
0091
0094
0127
0128
0137
0171
0185
Brasil
0160
0287
0387
0201
0170
0168
0339
So. Africa
0123
0155
0132
0127
0151
0089
0148
Cambior (Canada) sells to Canada, US and Japan. while Mineração Catalão (Anglo American Corporation) sales are directed mostly to US and Germany.
FUTURE TRENDS AND USES
Niobium  has been promoted, during the last 20 years into a very important component of the world steel industry.  Forecasters are predicting that the consumption will continue growing at the rate of 8-10%.

PREDICTED WORLD HIGH PURITY NIOBIUM METAL CONSUMPTION, 1981-2000


1981-1985
1986-2000

1
NMR AND LAB MAGNETS
25
175

2
HEP
40
80

3
COMPUTERS AND INSTRUMENTATION
2
18

4
MAGNETIC SEPARATION
1
2

5
SMES
4
16

6
LEVITATED TRAINS
-
4
subject to 1985 decision
7
SHIP PROPULSION
1
9

8
CURRENT LIMITERS
1
4

9
POWER TRANSMISSION
Negligible
70
mainly after 1944
10
SUPERCONDUCTING GENERATORS
1
11

11
FUSION
20
230

12
MHD
2
65

13
DEFENSE
5
50

14
GYROTRONS, ISOTOPE SEPARATORS
1
3


TOTAL
103
737

SEIS LAGOS, THE LARGEST RESOURCE
In 1975, during a geological mapping programme CPRM’s geologists discovered the remarkable structures of Seis Lagos Alkaline Complex intruded in gneissic terrain.  It comprises three different intrusive bodies.  Only in 1982 that company started a detailed exploration programme.
The main carbonatite is an outstanding topographic feature which stands 300m above the local surface (see picture).
Seis Lagos main structure has a 5km diameter and is situated at the São Gabriel da Cachoeira municipality at the Amazonas State, only 60km away from the Venezuelan border and 2km from a local road.  Seis Lagos is 97km from S. Gabriel port by the Negro River 900km upstream from Manaus.
The carbonatite is, also, characterized by its strong thorium anomaly which peaks at 35.344cps against a 1.300cps local background.
An intense supergene leaching process developed a 250m deep weathering profile.  This is the main reason why this deposit is so rich in niobium (2.81% Nb2O5), titanium and rare earths.
At Seis Lagos the niobium is present in minerals such as niobium-rutile and niobium-brookite together with florencite and crandalite (rare earths).
This unusual mineralogy is a result of the destruction of pyrochlore during the supergene process causing the free niobium to combine with oxigen, forming these oxides.  Niobium may be, also, in the structure of other supergene minerals such as goethite and hematite.
Technological studies have been made by CPRM and, apparently, the ore is amenable to treatment using known technology.  A technical report done by INBRACEL confirms that the use of SAM for direct reduction of Seis Lagos ore will allow the introduction of niobium in common low carbon steels, at a very low price, which may change all the economicity of this metal.
Reserves, calculated by CPRM, after a preliminary drilling programme, are listed below.
RESERVES
ORE (t)
GRADES (Nb2O5) %
Nb2O5 t
Measured
38,376,000
2.85
1,093,716
Indicated
200,640,000
2.40
4,815,360
Inferred
2,658,892,800
2.84
75,512,555
TOTAL
2,897,908,800
2.81
81,431,237

Since niobium is associated to titanium it is possible that titanium reserves may be as large as the niobium ones. 
CBMM, THE LARGEST PRODUCER
CBMM is the leading niobium producer of the world and is controlled by the, Brasil Warrant Adm.  De Bens e Empresas LTDA (Moreira Salles Group) with 55% and Molybdenum Corporation (Molycorp) with 45%.
CBMM produces about 65% of the world’s market and 100% of the Brazilian market with annual sales amounting to $150M.  This is one of the most profitable mining companies in Brazil today.

ORE (t)
GRADES (Nb2O5) %
Nb2O5 t
Measured
38,376,000
2.85
1,093,716
Indicated
200,640,000
2.40
4,815,360
Inferred
2,658,892,800
2.84
75,512,555
TOTAL
2,897,908,800
2.81
81,431,237

Since niobium is associated to titanium it is possible that titanium reserves may be as large as the niobium ones. 
CBMM, THE LARGEST PRODUCER
CBMM is the leading niobium producer of the world and is controlled by the, Brasil Warrant Adm.  De Bens e Empresas LTDA (Moreira Salles Group) with 55% and Molybdenum Corporation (Molycorp) with 45%.
CBMM produces about 65% of the world’s market and 100% of the Brazilian market with annual sales amounting to $150M.  This is one of the most profitable mining companies in Brazil today.

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